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Medium-Grade Phosphate Rock

brief introduction

P₂O₅ content: Usually between 24% and 30%
Characteristics: Contains a certain amount of impurities, and usually requires beneficiation (such as flotation, scrubbing, etc.) to meet the industrial usage standards.
Usage: After beneficiation, it can be used for the production of common superphosphate (SSP), calcium magnesium phosphate fertilizer, and other mid-to-low-end phosphate fertilizers. It can also be used as a blending raw material for high-grade ores.
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product information


Typical Chemical Specifications (Run-of-Mine Ore)


Component

Typical Range (Run-of-Mine)

Significance & Impact

P₂O₅

24% - 30%

The primary grade indicator. Defines the ore's core value.

CaO

35% - 45%

A primary constituent. The CaO/P₂O₅ mass ratio is key for acid consumption.

MgO

1.0% - 4.0%

The most critical harmful impurity. Increases acid viscosity, creates sludges, and severely disrupts wet-process phosphoric acid production.

Fe₂O₃

1.5% - 3.5%

Forms colloidal precipitates with Al₂O₃, causing filtration issues and affecting product color.

Al₂O₃

1.0% - 3.0%

Harmful impurity, often considered together with Fe₂O₃ as R₂O₃.

SiO₂

10% - 25%

Common gangue mineral. Content depends on the deposit type (e.g., siliceous vs. calcareous).

F

2.0% - 3.5%

An inherent companion element, recovered and managed to prevent environmental pollution.

LOI (Loss on Ignition)

3.0% - 8.0%

Indicates the content of volatile materials like organics and carbonates.

001


Beneficiation: The Path to a Usable Product

Target Specifications for Phosphate Concentrate (Post-Beneficiation):

Parameter

Target Specification (Concentrate)

P₂O₅

≥ 30% (Often targeted at 32%-35% or higher)

MgO

≤ 1.0% (High-quality concentrate requires ≤ 0.8%)

R₂O₃ (Fe₂O₃+Al₂O₃)

≤ 3.0%

Cd (Heavy Metals)

As low as possible, often ≤ 20-60 mg/kg P₂O₅ for environmental compliance

Particle Size

-200 mesh (-0.074mm) ≥ 80% (To ensure sufficient reaction surface area)

Moisture

≤ 10%


002

Primary Uses and Applications

Once beneficiated, the phosphate concentrate can be used for the same applications as high-grade rock:

  1. Fertilizer Production: The primary use. It is a key raw material for:

    • Di-ammonium Phosphate (DAP) and Mono-ammonium Phosphate (MAP)

    • Triple Superphosphate (TSP)

  2. Wet-Process Phosphoric Acid: The beneficiated concentrate is a standard feed material for acid production, which is then used to make fertilizers and industrial phosphate salts.

  3. Elemental Phosphorus Production: Can be used in electric arc furnaces, though it requires specific sizing (lump ore) and often a particular silica content.

Limited Direct Uses (Without Beneficiation):

  • Blending: Mixed with high-grade rock to reduce overall raw material cost.

  • Calcium Magnesium Phosphate Fertilizer: Directly used in this specific fertilizer process, which is more tolerant of impurities.

  • Direct Soil Application: Applied directly to acidic soils as a slow-release amendment, but this is inefficient and uncommon.



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