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High-Grade Phosphate Rock

brief introduction

P₂O₅ content: Usually ≥ 30%
Characteristics: Low impurity content, especially harmful impurities such as MgO, Fe₂O₃, and Al₂O₃. It can be directly used in the production of wet-process phosphoric acid.
Usage: High-end phosphatic fertilizers (such as diammonium phosphate DAP, monoammonium phosphate MAP), industrial-grade phosphoric acid, food-grade phosphoric acid, and fine phosphorus chemical products.
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product information


1. Chemical Composition Specifications

Component

Typical Specification

Significance & Impact

P₂O₅

≥ 30% (Premium: ≥ 32% - 36%)

The primary value driver. Higher content means lower ore and acid consumption per ton of phosphoric acid or fertilizer produced.

MgO

≤ 1.0% (Premium: ≤ 0.5%)

The most critical harmful impurity. Increases viscosity of phosphoric acid, creates unfilterable sludges, and severely disrupts plant operation.

Fe₂O₃ + Al₂O₃ (R₂O₃)

≤ 2.5% - 3.0%

Form colloidal precipitates that clog filters, increase P₂O₅ losses, and affect the color of the final product.

CaO

~ 45% - 52%

A primary constituent. The CaO/P₂O₅ mass ratio (ideal ~1.4-1.6) is key for predicting acid consumption.

SiO₂

Varies by deposit (e.g., 5% - 15%)

Inert gangue; provides a "skeleton" in the reaction slurry, but excess amounts add unnecessary load.

CO₂

≤ 3.0% - 4.0%

Indicates carbonate minerals (e.g., dolomite), which are associated with harmful MgO.

Cd (Cadmium)

≤ 20 mg/kg P₂O₅ (stricter in EU)

Critical environmental/safety指标. Heavy metals can enter the food chain through fertilizers.

Cl (Chloride)

≤ 0.1%

Highly corrosive to stainless steel equipment; must be strictly controlled.


2. Physical Specifications

Parameter

Typical Specification

Particle Size

For wet-process acid: -100 mesh (-0.15mm) or -200 mesh (-0.074mm) ≥ 80%.

Moisture

≤ 10.0% (Typically controlled at 8%-10% for handling and transport).

Appearance

Fine powder or granules, uniform color.



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3.Example of a Commercial High-Grade Phosphate Concentrate Specification

This is a typical example that might be used in an international sales contract.

Product: High-Grade Phosphate Concentrate

Item

Guarantee

Unit

Remarks

P₂O₅

34.0 (min)

%

Dry Basis

CaO

48.5

%

Dry Basis

MgO

0.6 (max)

%

Dry Basis, Critical Impurity

Fe₂O₃

1.0 (max)

%

Dry Basis

Al₂O₃

1.0 (max)

%

Dry Basis

SiO₂

10.0

%

Dry Basis

F

3.2 (max)

%

Dry Basis

CO₂

2.5 (max)

%

Dry Basis

Cd

15 (max)

mg/kg P₂O₅


Particle Size (-100 mesh)

85 (min)

%


Moisture

9.0 (max)

%

As Loaded


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